PPS (Polyphenylene Sulphide)

PPS β€” semi-crystalline high-performance polymer. 220 C service temperature, exceptional chemical resistance. For automotive fuel system components, chemical pump parts and electrical connectors.

Engineering Plastics High-Performance Polymer ISOPPS (ISO 10112) ENEN ISO 10112 ASTMD5313 (PPS) Trade NamesRyton (Solvay) / Fortron (Celanese) / Torelina (Toray) / Kepstan (Arkema) +8
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Description

PPS (Polyphenylene Sulphide) per ISO 10112 is a semi-crystalline thermoplastic with the best chemical resistance of any melt-processable engineering plastic combined with excellent flame retardance (V-0) and dimensional stability. Continuous service temperature 180-220 C. Used for automotive fuel system components, chemical pump parts, electrical connectors and PCB-mount components.

Key Properties β€” PPS Unfilled (standard)
Rm (Tensile Strength)
65 – 85
MPa
Re / Rp0.2 (Yield)
60 – 80
MPa
Aβ‚… (Elongation)
β‰₯ 2.0
%
E (Young's Modulus)
4
GPa
Density
1.36
g/cmΒ³
Main Designations (12)
Standard BodyDesignationCountry / RegionNote
ISO PPS (ISO 10112) International
EN EN ISO 10112 European Union
ASTM D5313 (PPS) USA
Trade Names Ryton (Solvay) / Fortron (Celanese) / Torelina (Toray) / Kepstan (Arkema) Global
Key Grades PPS unfilled / PPS GF40 (40% glass fibre) / PPS CF30 (carbon fibre) / PPS GF+Min Global
UL 94 V-0 (inherent flame retardance at 0.8 mm) USA
JIS PPS (JIS K 7209) Japan
GOST PPS (adopted) Russia / CIS
FDA 21 CFR 177.2490 (food contact β€” unfilled natural grades) USA
JUS PL-PPS Yugoslavia / Serbia Polyphenylene sulphide high-performance polymer
RoHS Compliant EU
Supply Forms Injection moulding compound (primary) + rod and sheet (stock shapes, less common) Global
Standards (12)
#Standard BodyDesignationCountry / RegionNote
1 ISO PPS (ISO 10112) International β€”
2 EN EN ISO 10112 European Union β€”
3 ASTM D5313 (PPS) USA β€”
4 Trade Names Ryton (Solvay) / Fortron (Celanese) / Torelina (Toray) / Kepstan (Arkema) Global β€”
5 Key Grades PPS unfilled / PPS GF40 (40% glass fibre) / PPS CF30 (carbon fibre) / PPS GF+Min Global β€”
6 UL 94 V-0 (inherent flame retardance at 0.8 mm) USA β€”
7 JIS PPS (JIS K 7209) Japan β€”
8 GOST PPS (adopted) Russia / CIS β€”
9 FDA 21 CFR 177.2490 (food contact β€” unfilled natural grades) USA β€”
10 JUS PL-PPS Yugoslavia / Serbia Polyphenylene sulphide high-performance polymer
11 RoHS Compliant EU β€”
12 Supply Forms Injection moulding compound (primary) + rod and sheet (stock shapes, less common) Global β€”
All values in wt.%
C
Carbon (phenylene sulphide backbone)
~63.7000
H
Hydrogen
~3.1800
S
Sulphur (thioether linkage)
~28.9000
O
Oxygen (trace)
Bal.
H2O
Water absorption (any condition)
≀ 0.0300
ElementSymbolMin %Max %Typical %
Carbon (phenylene sulphide backbone) C β€” β€” 63.7000
Hydrogen H β€” β€” 3.1800
Sulphur (thioether linkage) S β€” β€” 28.9000
Oxygen (trace) O β€” β€” β€”
Water absorption (any condition) H2O β€” 0.0300 β€”
Mechanical Properties
ConditionCode Rm min
MPa
Rm max
MPa
Re min
MPa
Re max
MPa
Aβ‚… min
%
Z
%
KV
J
HB minHB max HRC minHRC max E
GPa
PPS Unfilled (standard) STD 65 85 60 80 2.0 β€” β€” β€” β€” β€” β€” 3.8
PPS GF40 (40% glass fibre) GF40 130 170 115 155 1.0 β€” β€” β€” β€” β€” β€” 14.0
PPS CF30 (30% carbon fibre) CF30 150 190 140 175 1.0 β€” β€” β€” β€” β€” β€” 17.0
Physical Properties
Density
1.360
g/cmΒ³
Melting Point
270–285
Β°C
Young's Modulus
3.8
GPa
Poisson's Ratio
0.370
β€”
Thermal Conductivity
0.3
W/mΒ·K
Thermal Expansion
49.00
Γ—10⁻⁢ /K
Specific Heat
1,090
J/kgΒ·K
Magnetic
No
 
Heat Treatment
Annealing (crystallisation)
Temperature:200Β°C – 220Β°C
Medium:Circulating air oven
Duration:1-4 h
Cooling:Slow cool at 2 C/min
Hardness After:Increased crystallinity; better dim stability
Strongly recommended. Increases crystallinity from ~60% to ~65-70%, improving thermal and chemical resistance and reducing risk of blistering in chemical service.
Drying (optional but recommended)
Temperature:120Β°C – 135Β°C
Medium:Circulating air oven
Duration:3-4 h
Cooling:Sealed bag
Hardness After:Moisture <0.01%
PPS has very low water absorption β€” brief drying mainly for processing quality insurance.
Machinability
Machinability Rating
relative to AISI B1112 = 100%
100.0%
Good
Turning Speed (HSS)
350
m/min
Turning Speed (Carbide)
1,200
m/min
Feed Rate (Turning)
0.500
mm/rev
Drilling Speed (HSS)
300
m/min
Milling Speed (Carbide)
1,200
m/min
CoolantDry cutting or light MQL; no flood water needed
Chip FormationShort brittle chips (unfilled); abrasive dust (GF40)
Tool MaterialCarbide K10 (uncoated) for unfilled; PCD or very sharp carbide for GF40
Surface FinishRa 0.4-1.6 um
Good machinability in unfilled grade. GF40 extremely abrasive β€” PCD only. Moderate difficulty overall.
Applications
Automotive
Fuel system components (fuel pumps, injector housings, filter bodies), transmission control modules and under-hood electrical connectors operating at elevated temperatures.
Chemical Pumps
Pump impellers, casings and valve bodies for aggressive chemical service β€” withstands HCl, H2SO4 and many solvents.
Electronics / PCB
SMT solder-tolerant connectors, relay bodies and PCB-mount components requiring reflow soldering compatibility (260 C Tg compatible).
Aerospace
Electrical connector inserts, clamp components and fluid handling parts in aircraft wet bays.
Technical Notes
πŸ’§
Chemical Resistance
Outstanding β€” one of the best of all thermoplastics. Resists virtually all organic solvents, strong acids (including HCl, H2SO4), bases and fuels below 200 C. No known solvent below 200 C. Only fluorinated polymers (PTFE, PVDF) have broader resistance.
βœ…
vs PEEK
PPS: better chemical resistance at lower temperatures, significantly lower cost. PEEK: better mechanical properties, higher service temperature (250 C vs 220 C PPS). For most chemical service below 180 C: PPS is the cost-effective choice.
⚠️
Processing Brittleness
Unfilled PPS can be brittle β€” design with generous radii. GF40 is standard injection moulding grade for most structural applications.